Lutetium vanadate

Lutetium vanadate
Names
	Other names Lutetium vanadate(IV); Lutetium divanadate; Lutetium pyrovanadate
Identifiers
CAS Number	60571-03-1 ;
3D model (JSmol)	Interactive image;
	InChI InChI=1S/2Lu.7O.2V/q2+3;;6-1;; Key: MUHIQNGSKIUBKJ-UHFFFAOYSA-N;
	SMILES [Lu+3].[Lu+3].[O-][V]([O-])([O-])O[V]([O-])([O-])[O-];
Properties
Chemical formula	Lu2V2O7
Molar mass	563.818
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

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Lutetium vanadate is inorganic compound with ferromagnetic and semiconducting properties, with the chemical formula of Lu₂V₂O₇^[1] with the same structure as pyrochlore.^[2]

Preparation

Lutetium vanadate can be obtained by the reaction between lutetium oxide, vanadium trioxide and vanadium pentoxide at a high temperature (1400 °C) in an argon atmosphere with oxygen pressure of 2.0×10⁻⁵ bar.^[3]

2 Lu₂O₃ + V₂O₃ + V₂O₅ → 2 Lu₂V₂O₇

References

^ Ichikawa, Hirohiko; Kano, Luna; Saitoh, Masahiro; Miyahara, Shin; Furukawa, Nobuo; Akimitsu, Jun; Yokoo, Tetsuya; Matsumura, Takeshi; Takeda, Masayasu; Hirota, Kazuma (March 2005). "Orbital Ordering in Ferromagnetic Lu₂V₂O₇". Journal of the Physical Society of Japan. 74 (3): 1020–1025. arXiv:cond-mat/0502020. Bibcode:2005JPSJ...74.1020I. doi:10.1143/JPSJ.74.1020. S2CID 118927935.
^ Kitayama, Kenzo; Katsura, Takashi (5 August 1976). "A New Compound, Lu₂V₂O₇". Chemistry Letters. 5 (8): 815–816. doi:10.1246/cl.1976.815.
^ Haghighirad, A.A.; Gross, C.; Assmus, W. (April 2008). "Powder synthesis and crystal growth of Y₂V₂O₇ under high pressure and its physical properties". Journal of Crystal Growth. 310 (7–9): 2277–2283. Bibcode:2008JCrGr.310.2277H. doi:10.1016/j.jcrysgro.2007.10.069.

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[Ichikawa-1] Ichikawa, Hirohiko; Kano, Luna; Saitoh, Masahiro; Miyahara, Shin; Furukawa, Nobuo; Akimitsu, Jun; Yokoo, Tetsuya; Matsumura, Takeshi; Takeda, Masayasu; Hirota, Kazuma (March 2005). "Orbital Ordering in Ferromagnetic Lu₂V₂O₇". Journal of the Physical Society of Japan. 74 (3): 1020–1025. arXiv:cond-mat/0502020. Bibcode:2005JPSJ...74.1020I. doi:10.1143/JPSJ.74.1020. S2CID 118927935.

[2] Kitayama, Kenzo; Katsura, Takashi (5 August 1976). "A New Compound, Lu₂V₂O₇". Chemistry Letters. 5 (8): 815–816. doi:10.1246/cl.1976.815.

[3] Haghighirad, A.A.; Gross, C.; Assmus, W. (April 2008). "Powder synthesis and crystal growth of Y₂V₂O₇ under high pressure and its physical properties". Journal of Crystal Growth. 310 (7–9): 2277–2283. Bibcode:2008JCrGr.310.2277H. doi:10.1016/j.jcrysgro.2007.10.069.

[1]

Preparation

See also

References